Reverend Green graduated from Apex Technical College in New York City with an A.A.S Degree and Union Christian Bible Institute in Durham, North Carolina with a Bachelor's Degree in Theology.
Reverend Green served in the capacity of ordained Deacon at Duryea Presbyterian Church in Brooklyn, New York from 1977 to 1983, New Jerusalem Free Will Baptist Church, Durham, North Carolina from 1984-1990 and Union Chapel Missionary Baptist Church in Butner, North Carolina from 1990-1995.
He was licensed to preach on December 17, 1995, and preached his first sermon on the same day. He was ordained as a Baptist Minister on October 6, 1996, under the leadership of Pastor, Harold F. Trice, Sr. of Union Chapel Missionary Baptist Church of Butner, North Carolina and the East Cedar Grove Missionary Association of Creedmoor, North Carolina. Rev. Green has been the associate minister at Mount Bethel Baptist Church since 2000.
He has been married to the former Gloria A. Bennett for 40 years, and they have five children - Ben Holloway, Sakita Holloway (Sean), Malcoum Green (Lakisha), Tywana Green and Katrina Paschall (Gary). God has blessed them with ten grandchildren.
On April 14, 2013, Rev. Benjamin W. Green was installed as the fourteenth Pastor of Mount Bethel Baptist Church.
On April 5, 2014, Rev. Benjamin W. Green received his Honorary Doctor of Divinity Degree from Saint Thomas Christian University.